| | Volume One |
| A1 | –Berry Gordy | Intro: Berry Gordy | 2:26 |
| A2 | –Barrett Strong | Money (That's Want I Want) | 3:00 |
| A3 | –Smokey Robinson & The Miracles* | Intro: Smokey / Shop Around | 3:35 |
| A4 | –The Marvelettes | Intro: Katherine Anderson / Please Mr. Postman | 3:36 |
| A5 | –The Marvelettes | Intro: Katherine Anderson / Playboy | 3:12 |
| A6 | –Marvin Gaye | Intro: Marvin Gaye / Stubborn Kind Of Fellow | 3:28 |
| B1 | –Smokey Robinson & The Miracles* | Intro: Smokey / You've Really Got A Hold On Me | 3:01 |
| B2 | –Marvin Gaye | Intro: Marvin Gaye / Pride And Joy | 2:14 |
| B3 | –Stevie Wonder | Intro: Stevie Wonder / Fingertips | 3:51 |
| B4 | –Martha Reeves & The Vandellas | Intro: Martha Reeves / Come And Get These Memories | 3:33 |
| B5 | –Martha Reeves & The Vandellas | Intro: Martha Reeves / Love Is Like A Heat Wave | 3:07 |
| | Volume Two |
| C1 | –Smokey Robinson & The Miracles* | Intro: Smokey / Mickey's Monkey | 3:06 |
| C2 | –Marvin Gaye | Intro: Marvin Gaye / Can I Get A Witness | 3:23 |
| C3 | –Mary Wells | Intro: Smokey / My Guy | 3:27 |
| C4 | –Diana Ross & The Supremes* | Intro: Diana Ross / Where Did Our Love Go | 4:24 |
| C5 | –Martha Reeves & The Vandellas | Intro: Martha Reeves / Dancing In The Street | 3:06 |
| C6 | –The Four Tops* | Intro: Levi Stubbs / Baby I Need Your Loving | 3:39 |
| D1 | –Diana Ross & The Supremes* | Intro: Mary Wilson / Baby Love | 3:33 |
| D2 | –Diana Ross & The Supremes* | Come See About Me | 2:31 |
| D3 | –Marvin Gaye | Intro: Marvin Gaye / How Sweet It Is (To Be Loved By You) | 3:02 |
| D4 | –The Temptations | Intro: Otis Williams / My Girl | 4:08 |
| D5 | –Jr. Walker & The All Stars* | Intro: Jr. Walker / Shotgun | 3:04 |
| D6 | –Diana Ross & The Supremes* | Intro: Diana Ross / Stop! In The Name Of Love | 3:09 |
| | Volume Three |
| E1 | –Marvin Gaye | Intro: Marvin Gaye / I'll Be Doggone | 3:06 |
| E2 | –Diana Ross & The Supremes* | Intro: Mary Wilson / Back In My Arms Again | 3:24 |
| E3 | –The Four Tops* | Intro: Levi Stubbs / I Can't Help Myself | 2:46 |
| E4 | –Smokey Robinson & The Miracles* | Intro: Smokey / The Tracks Of My Tears | 3:01 |
| E5 | –Diana Ross & The Supremes* | Intro: Diana Ross / Nothing But Heartaches | 3:04 |
| E6 | –Diana Ross & The Supremes* | Intro: Diana Ross / I Hear A Symphony | 3:04 |
| F1 | –Stevie Wonder | Intro: Stevie Wonder / Uptight (Everything's Alright) | 3:06 |
| F2 | –Diana Ross & The Supremes* | Intro: Diana Ross / My World Is Empty Without You | 2:42 |
| F3 | –Martha Reeves & The Vandellas | Intro: Martha Reeves / My Baby Loves Me | 3:28 |
| F4 | –The Temptations | Intro: Otis Williams / Ain't Too Proud To Beg | 3:19 |
| F5 | –Jimmy Ruffin | What Becomes Of The Broken Hearted | 3:20 |
| F6 | –Diana Ross & The Supremes* | Intro: Diana Ross / You Can't Hurry Love | 2:58 |
| | Volume Four |
| G1 | –The Four Tops* | Intro: Levi Stubbs / Reach Out I'll Be There | 3:24 |
| G2 | –Diana Ross & The Supremes* | Intro: Diana Ross / You Keep Me Hangin' On | 2:51 |
| G3 | –The Four Tops* | Intro: Levi Stubbs / Standing In The Shadows Of Love | 3:02 |
| G4 | –The Four Tops* | Intro: Levi Stubbs / Bernadette | 3:17 |
| G5 | –Martha Reeves & The Vandellas | Intro: Martha Reeves / Jimmy Mack | 3:11 |
| G6 | –Marvin Gaye & Tammi Terrell | Intro: Marvin Gaye / Ain't No Mountain High Enough | 2:57 |
| G7 | –Stevie Wonder | Intro: Stevie Wonder / I Was Made To Love Her | 2:52 |
| H1 | –Diana Ross & The Supremes* | Intro: Mary Wilson / Reflections | 3:25 |
| H2 | –Gladys Knight And The Pips | Intro: Gladys Knight / I Heard It Through The Grapevine | 4:07 |
| H3 | –Smokey Robinson & The Miracles* | Intro: Smokey / I Second That Emotion | 3:15 |
| H4 | –The Temptations | Intro: Otis Williams / I Wish It Would Rain | 3:04 |
| H5 | –Diana Ross & The Supremes* | Intro: Diana Ross / Love Child | 2:51 |
| H6 | –Stevie Wonder | Intro: Stevie Wonder / For Once In My Life | 2:46 |
| H7 | –The Temptations | Intro: Otis Williams / Cloud Nine | 4:13 |
| | Volume Five |
| I1 | –Diana Ross & The Supremes* & The Temptations | Intro: Diana Ross / I'm Gonna Make You Love Me | 2:55 |
| I2 | –Marvin Gaye | Intro: Marvin Gaye / I Heard It Through The Grapevine | 3:18 |
| I3 | –Jr. Walker & The All Stars* | Intro: Jr. Walker / What Does It Take (To Win Your Love) | 2:56 |
| I4 | –The Originals | Intro: The Originals / Baby I'm For Real | 3:30 |
| I5 | –Jackson 5* | Intro: Michael Jackson / I Want You Back | 2:54 |
| I6 | –The Temptations | Intro: Otis Williams / Psychedelic Shack | 3:40 |
| J1 | –Diana Ross & The Supremes* | Intro: Diana Ross / Someday We'll Be Together | 5:35 |
| J2 | –Diana Ross & The Supremes* | Intro: Mary Wilson / Up The Ladder To The Roof | 3:45 |
| J3 | –Diana Ross | Intro: Diana Ross / Reach Out And Touch (Somebody's Hand) | 3:40 |
| J4 | –Diana Ross | Intro: Diana Ross / Ain't No Mountain High Enough | 6:15 |