The show's plot revolve around the story of Lord Shiva. This story of Lord Shiva traces his journey from being an ascetic to a family man.

During the creation of the world by Lord Brahma, Adi Shakti leaves Shiva from his Ardhanarishvara form. So to shape the universe she takes various births to marry Shiva but failed 106 times due to which Shiva becomes an ascetic. Hence Lord Brahma suggests his mind-born son Prajapati Daksh please Adi Shakti and ask her to incarnate as his daughter.

She takes birth as Daksh's daughter Sati. Meanwhile, Shiva cuts Brahma's fifth head making Daksh hate him. Sati falls for Shiva and finally marries him, much to Daksh's dismay. Hence, Daksh humiliates Shiva in front of Sati in his yagna. Sati being unable to tolerate this, sacrifices her life once again. So, Shiva orders Virabhadra to behead Daksh but later revive him on Prasuti's request and Shiva goes into deep meditation for centuries.

Adi Shakti then incarnates as Parvati, daughter of the Himavan and his wife Menavati, she is aware of her divinity as are her parents and grows up in Dadichi's Hermitage where she starts to call Mahadev as her husband which Menavati as a concerned mother dislikes strongly. Then Parvati grows up, and realises her divinity. She tries to realise Mahadev it is his wife Sati however, he rejects her and in process turns Kamadev to ashes his distraught wife, Rati curse Parvati. Parvati then agrees to marry as per her mother, Menavati's wish. However eventually Parvati and Himavan make Menavati realise who Parvati is who then agrees for this marriage, then Parvati meditates for 3000 years to please Mahadev to marry her. And finally, Mahadev and Parvati married. Later, Mahadev imparts some tantric knowledge to Parvati that helps her to take various forms like Nav Durga; Mahavidyas (Kali, Tara, Tripura Sundari, Bhuvaneshvari, Tripura Bhairavi, Chhinnamasta, Dhumavati, Bagalamukhi, Matangi and Kamala) and Matrikas to destroy various demons like Raktabija, Mahishasura, Shumbha Nishumbha, Chanda Munda, Durgmasura, Arunasura, Banasura, etc. Later, Shiva and Parvati extend their family to Karthikeya, Ganesha and Ashok Sundari.

The show also includes various forms of Mahadev including Virabhadra, Swami Adiyogi, Aghori, Bhoothnath, Vaidynaath, Bhairav, Rishabh, Pashupatinath, Kaal Bhairav, Baba Lokhnath, Shambhu, Nat Bhairav, Natraja, Martand, etc. in order to maintain sustainability in the universe, teaching humans moral values and slaying various asuras like Jalandhara, Andhak, Apasmarg, Vritrasura, Bhasmasura, Tripura, Shankachura, Nigaas, etc. The show also covers various folk stories of Lord Shiva to teach people moral values and ways to get moksha in the Kali Yuga. The supreme God protects common people from evil demons and uncompassionate rulers by taking various avatars in human form. The story of twelve Jyotirlinga is also shown completely.