Publisher Description

The definitive guide to organic coatings, thoroughly revised and updated—now with coverage of a range of topics not covered in previous editions Organic Coatings: Science and Technology, Fourth Edition offers unparalleled coverageof organic coatings technology and its many applications. Written by three leading industry experts (including a new, internationally-recognized coatings scientist) it presents a systematic survey of the field, revises and updates the material from the previous edition, and features new or additional treatment of such topics as superhydrophobic, ice-phobic, antimicrobial, and self-healing coatings; sustainability, artist paints, and exterior architectural primers. making it even more relevant and useful for scientists and engineers in the field, as well as for students in coatings courses.

The book incorporates up-to-date coverage of recent developments in the field with detailed discussions of the principles underlying the technology and their applications in the development, production, and uses of organic coatings. All chapters in this new edition have been updated to assure consistency and to enable extensive cross-referencing. The material presented is also applicable to the related areas of printing inks and adhesives, as well as areas within the plastics industry. This new edition

• Completely revises outdated chapters to ensure consistency and to enable extensive cross-referencing
• Correlates the empirical technology of coatings with the underlying science throughout
• Provides expert troubleshooting guidance for coatings scientists and technologists
• Features hundreds of illustrative figures and extensive references to the literature
• A new, internationally-recognized coatings scientist brings fresh perspective to the content.

Providing a broad overview for beginners in the field of organic coatings and a handy reference for seasoned professionals, Organic Coatings: Science and Technology, Fourth Edition, gives you the information and answers you need, when you need them.

Back Cover

THE DEFINITIVE GUIDE TO ORGANIC COATINGS, THOROUGHLY REVISED AND UPDATED--NOW WITH COVERAGE OF A RANGE OF TOPICS NOT COVERED IN PREVIOUS EDITIONS Organic Coatings: Science and Technology, Fourth Edition offers unparalleled coverage of organic coatings technology and its many applications. Written by three leading industry experts (including a new, internationally-recognized coatings scientist), the fourth edition presents a systematic survey of the field in which material from the previous edition is revised and updated. The fourth edition also features new or additional treatment of such topics as superhydrophobic, ice-phobic, antimicrobial, and self-healing coatings; sustainability, artist paints, and exterior architectural primers. making it even more relevant and useful for scientists and engineers in the field, as well as for students in coatings courses. The book incorporates up-to-date coverage of recent developments in the field with detailed discussions of the principles underlying the technology and their applications in the development, production, and uses of organic coatings. All chapters in this new edition have been updated to assure consistency and to enable extensive cross-referencing. The material presented is also applicable to the related areas of printing inks and adhesives, as well as areas within the plastics industry. This new edition: Completely revises outdated chapters to ensure consistency and to enable extensive cross-referencing Correlates the empirical technology of coatings with the underlying science throughout Provides expert troubleshooting guidance for coatings scientists and technologists Features hundreds of illustrative figures and extensive references to the literature A new, internationally-recognized coatings scientist brings fresh perspective to the content. Providing a broad overview for beginners in the field of organic coatings and a handy reference for seasoned professionals, Organic Coatings: Science and Technology, Fourth Edition , gives you the information and answers you need, when you need them.

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THE DEFINITIVE GUIDE TO ORGANIC COATINGS, THOROUGHLY REVISED AND UPDATED--NOW WITH COVERAGE OF A RANGE OF TOPICS NOT COVERED IN PREVIOUS EDITIONS Organic Coatings: Science and Technology, Fourth Edition offers unparalleled coverage of organic coatings technology and its many applications. Written by three leading industry experts (including a new, internationally-recognized coatings scientist), the fourth edition presents a systematic survey of the field in which material from the previous edition is revised and updated. The fourth edition also features new or additional treatment of such topics as superhydrophobic, ice-phobic, antimicrobial, and self-healing coatings; sustainability, artist paints, and exterior architectural primers. making it even more relevant and useful for scientists and engineers in the field, as well as for students in coatings courses. The book incorporates up-to-date coverage of recent developments in the field with detailed discussions of the principles underlying the technology and their applications in the development, production, and uses of organic coatings. All chapters in this new edition have been updated to assure consistency and to enable extensive cross-referencing. The material presented is also applicable to the related areas of printing inks and adhesives, as well as areas within the plastics industry. This new edition: Completely revises outdated chapters to ensure consistency and to enable extensive cross-referencing Correlates the empirical technology of coatings with the underlying science throughout Provides expert troubleshooting guidance for coatings scientists and technologists Features hundreds of illustrative figures and extensive references to the literature A new, internationally-recognized coatings scientist brings fresh perspective to the content. Providing a broad overview for beginners in the field of organic coatings and a handy reference for seasoned professionals, Organic Coatings: Science and Technology, Fourth Edition , gives you the information and answers you need, when you need them.

Author Biography

FRANK N. JONES is a consultant and an Emeritus Professor at Eastern Michigan University, where he was Director, of the National Science Foundation Industry/University Cooperative Research Center in Coatings. Previously he was Professor and Chair of the Department of Polymers and Coatings at North Dakota State University. MARK E. NICHOLS is currently Technical Leader, Paint and Corrosion Research at the Ford Motor Company and the Editor-in-Chief of the Journal of Coatings Technology and Research. He is the recipient of the Industry Excellence Award from the ACA as well as a Roon Award. SOCRATES PETER PAPPAS is a consultant. Previously he was Corporate Scientist at Kodak Polychrome Graphics, Director of Chemical Imaging at Polychrome Corporation, Scientific Fellow at Loctite Corporation, and Professor at North Dakota State University in the Departments of Chemistry, as well as Polymers and Coatings.

Table of Contents

Preface xi 1. Introduction to Coatings 1 1.1 Definitions and Scope 1 1.2 Types of Coatings 3 1.3 Composition of Coatings 3 1.4 Coating History 4 1.5 Commercial Considerations 5 References 5 2. Polymerization and Film Formation 6 2.1 Polymers 6 2.2 Polymerization 13 2.3 Film Formation 19 References 27 3. Flow 29 3.1 Shear Flow 29 3.2 Types of Shear Flow 30 3.3 Determination of Shear Viscosity 32 3.4 Shear Viscosity of Resin Solutions 36 3.5 Viscosity of Liquids With Dispersed Phases 40 3.6 Other Modes of Flow 42 References 44 4. Mechanical Properties 46 4.1 Introduction 46 4.2 Basic Mechanical Properties 46 4.3 Fracture Mechanics 57 4.4 Abrasion, Scratch, and Mar Resistance 58 4.5 Measurement of Mechanical Properties 61 4.6 Tests of Coatings on Substrates 62 References 66 5. Exterior Durability 67 5.1 Photoinitiated Oxidative Degradation 67 5.2 Photostabilization 70 5.3 Degradation of Chlorinated Resins 75 5.4 Hydrolytic Degradation 75 5.5 Other Modes of Failure on Exterior Exposure 77 5.6 Testing for Exterior Durability 78 5.7 Service Life Prediction 84 References 84 6. Adhesion 86 6.1 Mechanisms of Adhesion 86 6.2 Mechanical Stresses and Adhesion 89 6.3 Adhesion to Metal Surfaces 90 6.4 Characterization of Surfaces 92 6.5 Organic Chemical Treatment of Substrates to Enhance Adhesion 93 6.6 Covalent Bonding to Glass and Metal Substrates 94 6.7 Adhesion to Plastics and to Coatings 95 6.8 Testing for Adhesion 96 References 98 7. Corrosion Protection by Coatings 99 7.1 Corrosion Basics 99 7.2 Corrosion of Uncoated Steel 100 7.3 Corrosion Protection of Metals 101 7.4 Corrosion Protection by Intact Coatings 103 7.5 Corrosion Protection by Nonintact Films 107 7.6 Evaluation and Testing 111 References 113 8. Acrylic Resins 115 8.1 Thermoplastic Acrylic Resins 115 8.2 Thermosetting Acrylic Resins 116 8.3 Water]Reducible Thermosetting Acrylic Resins 121 References 124 9. Latexes 125 9.1 Emulsion Polymerization 125 9.2 Acrylic Latexes 133 9.3 Vinyl Ester Latexes 135 9.4 Thermosetting Latexes 137 References 139 10. Polyester Resins 141 10.1 Hydroxy]Terminated Polyester Resins for Conventional Solids Coatings 142 10.2 Polyester Resins for High Solids Coatings 146 10.3 Carboxylic Acid]Terminated Polyester Resins 147 10.4 Carbamate]Functional Polyester Resins 148 10.5 Water]Reducible Polyester Resins 148 10.6 Polyester Resins for Powder Coatings 149 References 150 11. Amino Resins 151 11.1 Synthesis of Melamine–Formaldehyde Resins 151 11.2 Types of MF Resins 154 11.3 MF–Polyol Reactions in Coatings 155 11.4 Other Amino Resins 161 References 162 12. Polyurethanes and Polyisocyanates 163 12.1 Reactions of Isocyanates 164 12.2 Kinetics of Reactions of Isocyanates with Alcohols 165 12.3 Isocyanates Used in Coatings 170 12.4 Two]Package (2K) Solventborne Urethane Coatings 173 12.5 Blocked Isocyanates 176 12.6 Moisture]Curable Urethane Coatings 181 12.7 Waterborne Polyurethane Coatings 182 12.8 Hydroxy]Terminated Polyurethanes 185 References 186 13. Epoxy and Phenolic Resins 188 13.1 Epoxy Resins 188 13.2 Amine Cross]Linked Epoxy Resins 193 13.3 Other Cross]Linking Agents for Epoxy Resins 199 13.4 Water]Reducible Epoxy/Acrylic Graft Copolymers: Epoxy/Acrylic Hybrids 201 13.5 Epoxy Resin Phosphate Esters 202 13.6 Phenolic Resins 202 References 204 14. Drying Oils 205 14.1 Compositions of Natural Oils 205 14.2 Autoxidation and Cross]Linking 206 14.3 Synthetic and Modified Drying Oils 209 References 211 15. Alkyd Resins 213 15.1 Oxidizing Alkyds 214 15.2 High Solids Oxidizing Alkyds 217 15.3 Waterborne Oxidizing Alkyds 218 15.4 Nonoxidizing Alkyds 220 15.5 Synthetic Procedures for Alkyd Resins 220 15.6 Modified Alkyds 223 15.7 Uralkyds and Other Autoxidizable Urethanes 224 15.8 Epoxy Esters 225 References 226 16. Silicon Derivatives 228 16.1 Silicones 228 16.2 Reactive Silanes 232 16.3 Orthosilicates 233 References 234 17. Other Resins and Cross]Linkers 235 17.1 Halogenated Polymers 235 17.2 Cellulose Derivatives 237 17.3 Unsaturated Polyester Resins 238 17.4 (Meth)Acrylated Oligomers 240 17.5 2]Hydroxyalkylamide Cross]Linkers 240 17.6 Acetoacetate Cross]Linking Systems 241 17.7 Polyaziridine Cross]Linkers 242 17.8 Polycarbodiimide Cross]Linkers 242 17.9 Polycarbonates 243 17.10 Non]Isocyanate Two]Package Binders 243 17.11 Dihydrazides 244 References 244 18. Solvents 246 18.1 Solvent Composition 246 18.2 Solubility 247 18.3 Solvent Evaporation Rates 251 18.4 Viscosity Effects 257 18.5 Flammability 258 18.6 Other Physical Properties 259 18.7 Toxic Hazards 259 18.8 Atmospheric Photochemical Effects 260 18.9 Regulation of Solvent Emissions from Coatings 262 References 265 19. Color and Appearance 267 19.1 Light 267 19.2 Light–Object Interactions 268 19.3 Hiding 274 19.4 Metallic and Interference Colors 275 19.5 The Observer 276 19.6 Interactions of Light Source, Object, and Observer 277 19.7 Color Systems 277 19.8 Color Mixing 281 19.9 Color Matching 281 19.10 Gloss 286 References 292 20. Pigments 293 20.1 White Pigments 293 20.2 Color Pigments 296 20.3 Inert Pigments 302 20.4 Functional Pigments 303 20.5 Nano]Pigments 304 References 305 21. Pigment Dispersion 307 21.1 Dispersion in Organic Media 307 21.2 Formulation of Nonaqueous Mill Bases 311 21.3 Dispersion in Aqueous Media 313 21.4 Dispersion Equipment and Processes 315 21.5 Evaluation of Dispersions 320 References 322 22. Effect of Pigments on Coating Properties 323 22.1 PVC and CPVC 323 22.2 Relationships Between Film Properties and PVC 326 References 330 23. Application Methods 331 23.1 Brushes, Pads, and Hand Rollers 331 23.2 Spray Application 332 23.3 Dip and Flow Coating 338 23.4 Roll Coating 339 23.5 Curtain Coating 340 References 341 24. Film Defects 342 24.1 Surface Tension 342 24.2 Leveling 344 24.3 Sagging and Drip Marks 346 24.4 Crawling, Cratering, and Related Defects 348 24.5 Floating and Flooding: Hammer Finishes 351 24.6 Wrinkling: Wrinkle Finishes 352 24.7 Bubbling and Popping 353 24.8 Foaming 354 24.9 Dirt 355 References 355 25. Solventborne and High Solids Coatings 357 25.1 Primers 358 25.2 Top Coats 360 References 365 26. Waterborne Coatings 366 26.1 Water]Reducible Coatings 367 26.2 Latex]based Coatings 369 26.3 Emulsion Coatings 371 References 372 27. Electrodeposition Coatings 374 27.1 Anionic Electrodeposition Coatings 375 27.2 Cationic Electrodeposition Coatings 376 27.3 Effect of Variables on Electrodeposition 378 27.4 Application of Electrodeposition Coatings 380 27.5 Advantages and Disadvantages of Electrodeposition 381 27.6 Autodeposition Coatings 383 References 383 28. Powder Coatings 385 28.1 Binders for Thermosetting Powder Coatings 385 28.2 Binders for Thermoplastic Powder Coatings 390 28.3 Formulation of Thermosetting Powder Coatings 391 28.4 Manufacture of Powder Coatings 394 28.5 Application Methods 396 28.6 Advantages and Limitations 400 References 401 29. Radiation Cure Coatings 403 29.1 UV Curing 404 29.2 Free Radical]Initiated UV Cure 406 29.3 Cationic UV Cure 412 29.4 Hybrid Free Radical/Cationic Polymerization 413 29.5 Effects of Pigmentation 414 29.6 Electron Beam Cure Coatings 415 29.7 Dual UV/Thermal Cure 415 29.8 Selected Applications 416 29.9 Advantages, Disadvantages, and Selected Advances 416 References 418 30. Product Coatings for Metal Substrates 419 30.1 OEM Automotive Coatings 419 30.2 Appliance Coatings 427 30.3 Container Coatings 427 30.4 Coil Coating 431 30.5 Coatings for Aircraft 435 References 436 31. Product Coatings for Nonmetallic Substrates 438 31.1 Coatings for Wood 438 31.2 Coating of Plastics 444 References 448 32. Architectural Coatings 449 32.1 Exterior House Paints and Primers 450 32.2 Flat and Semigloss Interior Paints 455 32.3 Gloss Enamels 459 References 463 33. Special Purpose Coatings 464 33.1 Maintenance Paints 464 33.2 Marine Coatings 471 33.3 Automobile Refinish Paints 474 33.4 Traffic Striping Paints 477 References 478 34. Functional Coatings 480 34.1 Superhydrophobic and Superhydrophilic Coatings 480 34.2 Ice]Phobic Coatings 483 34.3 Self]Healing Coatings 484 34.4 Environmentally Sensing Coatings 485 34.5 Antimicrobial Coatings 486 References 486 Index 488

Long Description

THE DEFINITIVE GUIDE TO ORGANIC COATINGS, THOROUGHLY REVISED AND UPDATED NOW WITH COVERAGE OF A RANGE OF TOPICS NOT COVERED IN PREVIOUS EDITIONS Organic Coatings: Science and Technology, Fourth Edition offers unparalleled coverage of organic coatings technology and its many applications. Written by three leading industry experts (including a new, internationally-recognized coatings scientist), the fourth edition presents a systematic survey of the field in which material from the previous edition is revised and updated. The fourth edition also features new or additional treatment of such topics as superhydrophobic, ice-phobic, antimicrobial, and self-healing coatings; sustainability, artist paints, and exterior architectural primers. making it even more relevant and useful for scientists and engineers in the field, as well as for students in coatings courses. The book incorporates up-to-date coverage of recent developments in the field with detailed discussions of the principles underlying the technology and their applications in the development, production, and uses of organic coatings. All chapters in this new edition have been updated to assure consistency and to enable extensive cross-referencing. The material presented is also applicable to the related areas of printing inks and adhesives, as well as areas within the plastics industry. This new edition: Completely revises outdated chapters to ensure consistency and to enable extensive cross-referencing Correlates the empirical technology of coatings with the underlying science throughout Provides expert troubleshooting guidance for coatings scientists and technologists Features hundreds of illustrative figures and extensive references to the literature A new, internationally-recognized coatings scientist brings fresh perspective to the content. Providing a broad overview for beginners in the field of organic coatings and a handy reference for seasoned professionals, Organic Coatings: Science and Technology, Fourth Edition , gives you the information and answers you need, when you need them.

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