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Citrulline is a non-essential amino acid, a precursor of creatine, converted to glycemic amine and arginine. Participates in the synthesis of nitric oxide (NO) by stimulating its production.
Nitric oxide causes capillaries to widen, which in turn increases blood flow. 
Increased blood flow brings a lot of benefits to the muscles undergoing exercise.
The most important benefits of Citrulline Malate supplementation are: