Most computers will boot from USB automatically:
• Insert the USB flash drive
• Restart your computer
If your computer doesn’t automatically boot from USB, try holding F12 when your computer first starts. With most machines, this will allow you to select the USB device from a system-specific boot menu.
F12 is the most common key for bringing up your system’s boot menu, but both Escape and F2 are typical alternatives. If you’re unsure, look for a brief message when your system starts - this will often inform you of which key to press to bring up the boot menu.
From Windows:
Make the computer start on the USB stick
1. Click on the Start button.
2. Press and hold the Shift key while you choose Power ▸ Restart.
3. In the Choose an option screen, choose Use a device.
4. In the Use a device screen, choose Boot Menu.
5. In the Boot Menu, select your USB stick and press Enter.