#define VOLTAGE 5.00 //system voltage
#define OFFSET 0 //zero drift voltage
#define LED 13 //operating instructions
double orpValue;
#define ArrayLenth 40 //times of collection
#define orpPin 1 //orp meter output,connect to Arduino controller ADC pin
int orpArray[ArrayLenth];
int orpArrayIndex=0;
double avergearray(int* arr, int number){
int i;
int max,min;
double avg;
long amount=0;
if(number<=0){
printf("Error number for the array to avraging!/n");
return 0;
}
if(number<5){ //less than 5, calculated directly statistics
for(i=0;i<number;i++){
amount+=arr[i];
}
avg = amount/number;
return avg;
}else{
if(arr[0]<arr[1]){
min = arr[0];max=arr[1];
}
else{
min=arr[1];max=arr[0];
}
for(i=2;i<number;i++){
if(arr[i]<min){
amount+=min; //arr<min
min=arr[i];
}else {
if(arr[i]>max){
amount+=max; //arr>max
max=arr[i];
}else{
amount+=arr[i]; //min<=arr<=max
}
}//if
}//for
avg = (double)amount/(number-2);
}//if
return avg;
}
void setup(void) {
Serial.begin(9600);
pinMode(LED,OUTPUT);
}
void loop(void) {
static unsigned long orpTimer=millis(); //analog sampling interval
static unsigned long printTime=millis();
if(millis() >= orpTimer)
{
orpTimer=millis()+20;
orpArray[orpArrayIndex++]=analogRead(orpPin); //read an analog value every 20ms
if (orpArrayIndex==ArrayLenth) {
orpArrayIndex=0;
}
orpValue=((30*(double)VOLTAGE*1000)-(75*avergearray(orpArray, ArrayLenth)*VOLTAGE*1000/1024))/75-OFFSET;
//convert the analog value to orp according the circuit
}
if(millis() >= printTime) //Every 800 milliseconds, print a numerical, convert the state of the LED indicator
{
printTime=millis()+800;
Serial.print("ORP: ");
Serial.print((int)orpValue);
Serial.println("mV");
digitalWrite(LED,1-digitalRead(LED));
}
}
Precautions
Before and after measurement, it is necessary to use deionized water to wash the electrode, in order to ensure precision. When measured in thick samples, you should wash the electrode with hot deionized water and repeatedly rinsed several times to remove anything sticking to the platinum Sheet specimen.
Passivation will occur when the electrode has been used for a long time. The phenomenon can be seen when the sensitivity gradient decreases, has slow responses, or is reading data is not accurate. At this time, you should immerse the bottom electrode platinum sheet into 0.1M hydrochloric acid for 24 hours.
Electrode pollution or the liquid junction jam also can make the electrode passivation. At this time, you should select the appropriate cleaning solution based on the nature of the pollutant.
The electrode use cycle is about one year. After aging, it should be replaced with a new electrode in a timely manner.