| New Orchestrated Album | |
| CD1-1 | Freddie Mercury & Montserrat Caballé– | Barcelona | 5:44 |
| CD1-2 | Freddie Mercury & Montserrat Caballé– | La Japonaise | 4:52 |
| CD1-3 | Freddie Mercury & Montserrat Caballé– | The Fallen Priest | 5:46 |
| CD1-4 | Freddie Mercury & Montserrat Caballé– | Ensueño | 4:22 |
| CD1-5 | Freddie Mercury & Montserrat Caballé– | The Golden Boy | 6:03 |
| CD1-6 | Freddie Mercury & Montserrat Caballé– | Guide Me Home | 2:50 |
| CD1-7 | Freddie Mercury & Montserrat Caballé– | How Can I Go On | 3:49 |
| CD1-8 | Freddie Mercury & Montserrat Caballé– | Exercises In Free Love | 3:57 |
| CD1-9 | Freddie Mercury & Montserrat Caballé– | Overture Piccante | 6:47 |
| | Bonus Track | |
| CD1-10 | Freddie Mercury & Montserrat Caballé Feat. David Garrett (4)– | How Can I Go On | 3:59 |
| | The Best Of The Rarities And Session Out-Takes | |
| CD2-1 | Montserrat Caballé– | Exercises In Free Love (1987 B-Side: Montserrat's Vocal) | 4:28 |
| CD2-2 | Freddie Mercury– | Barcelona (Early Version: Freddie's Demo Vocal) | 4:21 |
| CD2-3 | Freddie Mercury– | La Japonaise (Early Version: Freddie's Demo Vocal) | 4:41 |
| CD2-4 | Freddie Mercury– | Rachmaninov's Revenge (The Fallen Priest - Later Version: Freddie's Demo Vocal) | 5:51 |
| CD2-5 | Montserrat Caballé– | Ensueño (Montserrat's Live Takes) | 5:36 |
| CD2-6 | Freddie Mercury– | The Golden Boy (Early Version: Freddie's Demo Vocal) | 3:54 |
| CD2-7 | Freddie Mercury– | Guide Me Home (Alternative Version) | 2:50 |
| CD2-8 | Freddie Mercury– | How Can I Go On (Alternative Version) | 4:04 |
| CD2-9 | Freddie Mercury– | How Can I Go On (Alternative Piano Version) | 3:47 |
| | DVD | |
| DVD-1 | Freddie Mercury & Montserrat Caballé– | Barcelona (Ku Club Ibiza Performance) | 4:23 |
| DVD-2 | Freddie Mercury & Montserrat Caballé– | Barcelona (La Nit Performance) | 5:48 |
| DVD-3 | Freddie Mercury & Montserrat Caballé– | How Can I Go On (La Nit Performance) | 3:48 |
| DVD-4 | Freddie Mercury & Montserrat Caballé– | The Golden Boy (La Nit Performance) | 6:02 |
| DVD-5 | Freddie Mercury & Montserrat Caballé– | Barcelona (Classic Video) | 4:29 |
| DVD-6 | Freddie Mercury & Montserrat Caballé– | Barcelona Special Edition (Mini Documentary) | 5:34 |
| DVD-7 | Freddie Mercury & Montserrat Caballé– | Barcelona (2012 Edit) | 4:29 |
| | Album Orchestral Version | |
| CD3-1 | Freddie Mercury & Montserrat Caballé– | Barcelona | 5:40 |
| CD3-2 | Freddie Mercury & Montserrat Caballé– | La Japonaise | 4:51 |
| CD3-3 | Freddie Mercury & Montserrat Caballé– | The Fallen Priest | 5:47 |
| CD3-4 | Freddie Mercury & Montserrat Caballé– | Ensueño | 4:01 |
| CD3-5 | Freddie Mercury & Montserrat Caballé– | The Golden Boy | 6:04 |
| CD3-6 | Freddie Mercury & Montserrat Caballé– | Guide Me Home | 2:50 |
| CD3-7 | Freddie Mercury & Montserrat Caballé– | How Can I Go On | 3:37 |
| CD3-8 | Freddie Mercury & Montserrat Caballé– | Exercises In Free Love | 3:57 |
| CD3-9 | Freddie Mercury & Montserrat Caballé– | Overture Piccante | 6:45 |