A DVD was released at the same time as the CD editions. The sleeve artwork is the same, but the track listing is chronological.

There are bonus videos including: both videos for "Opportunities (Let's Make Lots of Money)"; "Paninaro", which was released as a single in Italy; "How Can You Expect to Be Taken Seriously?" (brothers in rhythm remix) and "Was It Worth It?", which do not appear on the CD; "London", which was only released as a single in Germany; and extended videos for "Domino Dancing", "So Hard" and "Go West". The only video that is missing is the 1994 Comic Relief single "Absolutely Fabulous", which remains unavailable on DVD due to licensing hurdles.

The videos to "Miracles" and "Flamboyant" were not ready when the DVD went to press, so they were not included. They were released along with the videos for "I'm with Stupid", "Minimal" and "Numb" on the Pet Shop Boys: A Life in Pop documentary DVD.

The DVD also features a commentary by Neil Tennant, Chris Lowe and Chris Heath.

  1. "Opportunities (Let's Make Lots of Money)" (original version)
  2. "West End Girls"
  3. "Love Comes Quickly"
  4. "Opportunities (Let's Make Lots of Money)" (second version)
  5. "Suburbia"
  6. "Paninaro"
  7. "It's a Sin"
  8. "What Have I Done to Deserve This?"
  9. "Rent"
  10. "Always on My Mind"
  11. "Heart"
  12. "Domino Dancing"
  13. "Left to My Own Devices"
  14. "It's Alright"
  15. "So Hard"
  16. "Being Boring"
  17. "How Can You Expect to Be Taken Seriously?"
  18. "Where the Streets Have No Name (I Can't Take My Eyes Off You)"
  19. "Jealousy"
  20. "DJ Culture"
  21. "Was It Worth It?"
  22. "Can You Forgive Her?"
  23. "Go West"
  24. "I Wouldn't Normally Do This Kind of Thing"
  25. "Liberation"
  26. "Yesterday, When I Was Mad"
  27. "Paninaro '95"
  28. "Before"
  29. "Se a Vida É (That's the Way Life Is)"
  30. "Single-Bilingual"
  31. "A Red Letter Day"
  32. "Somewhere"
  33. "I Don't Know What You Want but I Can't Give It Any More"
  34. "New York City Boy"
  35. "You Only Tell Me You Love Me When You're Drunk"
  36. "Home and Dry"
  37. "I Get Along/E-mail"
  38. "London"
  39. "Domino Dancing" (extended version) [The 12" and Introspective Mix]
  40. "So Hard" (extended version) [The "Extended Dance Mix"]
  41. "Go West" (extended version) [The Mings Gone West: First and Second Movement Video Mix]