This is a single card from the Set 'British Rock Stars' issued by Legends Wall of Fame in 1992.
In the 1990s is was common for people to have framed sets of vintage cigarette cards on the walls of UK homes. There was some demand for sets to cover slightly more topical subjects tham 'University Hoods and Gowns' and 'Pipes of the World. This set was one of many produced to meet that demand. The card size thus corresponds to Large (L) sized cigarette cards which were usually issued in sets of 25.
The rest of the set as well as 1000s of other pop and rock related cards and stickers can be found by viewing my other items.